Dr. anand Burange » Публикация
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Опубликовано
2013-05-22
Опубликовано на SciPeople2013-06-01 22:55:12
ЖурналCatalysis Communications
Oxidation of benzylic alcohols to carbonyls using tert-butyl hydroperoxide over pure phase nanocrystalline CeCrO3
DOI NO. 10.1016/j.catcom.2013.05.019
Аннотация
Nanocrystalline phase pure CeCrO3 was synthesized by a two step preparation method. The
prepared material was characterized by techniques such as X-Ray Diffraction (XRD), High
Resolution Transmission Electron Microscopy (HR-TEM), EDX and SEM analysis. The
catalytic activity of CeCrO3 was investigated for the oxidation of benzylic alcohols to the
corresponding carbonyls using TBHP as oxidant. Oxidation of several structurally diverse
primary and secondary benzylic alcohols were studied with the CeCrO3/TBHP catalytic system.
The catalyst exhibited significant catalytic activity and selectivity in most of the cases.